Recent Advances in Electrochemical Synthesis of Hydrogen Peroxide
DOI: https://doi.org/10.62381/I245201
Author(s)
Shengliang Li
Affiliation(s)
Zhengzhou University, Zhengzhou, Henan, China
Abstract
Hydrogen peroxide stands as a valuable, eco-friendly, versatile oxidizing agent that is widely used in chemical synthesis, industrial product bleaching, and wastewater treatment. At present, the anthraquinone method is the main method for synthesizing H2O2 in large quantities in industry. However, this method has the disadvantages of high cost, excessive energy consumption, intricate procedures, and significant emissions of pollutants are notable. It is not suitable for on-site preparation on demand, and the products prepared by the anthraquinone method are not suitable for on-site preparation. Safety hazards are prone to occur during storage and transportation. Using electrocatalysts to synthesize H2O2, attainable via either the two-electron oxygen reduction reaction or the water oxidation reaction On-site on-demand preparation of hydrogen peroxide. It is a promising alternative method that has attracted attention in recent years. This article briefly introduces the reaction mechanism, catalyst design, and application development of electrochemical synthesis of H2O2.
Keywords
Hydrogen Peroxide; Electrocatalytic; Electrochemistry; Synthesis; Catalyst
References
[1] XL Tang, F Li, F Li, et al. (2023) Single-atom catalysts for the photocatalytic and electrocatalytic synthesis of H2O2, Chinese Journal of Catalysis, 52: 79-98.
[2] JM Zhang, M Chaker and DL Ma. (2017) Pulsed laser ablation based synthesis of colloidal metal nanoparticles for catalytic applications, Journal of Colloid and Interface Science, 489: 138-149.
[3] JY Zhang, C Xia, HF Wang, et al. (2022) Recent advances in electrocatalytic oxygen reduction for on-site H2O2 synthesis in acidic media, Journal of Energy Chemistry, 67: 432-450.
[4] ZH Xue, DY Luan, HB Zhang, et al. (2022) Catalysts composed of single atoms are employed for the conversion of solar energy into usable forms, Joule, 6: 92-133.
[5] QN Zhan, TY Shuai, HM Xu, et al. (2023) Syntheses and applications of single-atom catalysts for electrochemical energy conversion reactions, Chinese Journal of Catalysis, 47: 32-66.
[6] L Zhao, QL Zhao, J Zhang, et al. (2021) Review on studies of the emptying process of compressed hydrogen tanks, International Journal of Hydrogen Energy, 46(43): 22444-22573.
[7] Q Zhang, MS Sun, MQ Yao, et al. (2022) Interfacial engineering of an FeOOH@Co3O4 heterojunction for efficient overall water splitting and electrocatalytic urea oxidation, Journal of Colloid and Interface Science, 623: 617-626.
[8] AM Carlos & F Sergio. (2006) Electrochemical oxidation of organic pollutants for the wastewater treatment: direct and indirect processes, Chemical Society Reviews, 35(12): 1324-1340.
[9] MC Jose, B Gema, and LG Jose. (2006) Fierro Hydrogen Peroxide synthesis: an outlook beyond the anthraquinone process, Angewandte Chemie International Edition, 45(42): 6962-6984.
[10] SC Yang, SH Pang, TP Sulmonetti, et al. (2018) Synergy between Ceria Oxygen Vacancies and Cu Nanoparticles Facilitates the Catalytic Conversion of CO2 to CO under Mild Conditions, ACS Catal., 8(12): 12056-12066.
[11] YY Sun, L Han and P Strasser. (2020) A comparative perspective of electrochemical and photochemical approaches for catalytic H2O2 production, Chemical Society Reviews, 49: 6605-6631.
[12] JY Wang, Y Wang, DH Seo, et al. (2020) A High-Energy NASICON-Type Cathode Material for Na-Ion Batteries, Advanced Energy Materials, 10(10): 1903968.
[13] M Dan, RY Zhong, SY Hu, et al. (2022) Strategies and challenges on selective electrochemical H2O2 production: Catalyst and reaction medium design, Chem Catalysis, 2(8): 1919-1960.
[14] ZY Wen, N Han and YG Li. (2024) Advancements in the Electrochemical Two-Electron Oxygen Reduction Reaction for the Production of Hydrogen Peroxide, Acta Physico-Chimica Sinica, 40 (X): 2304001
[15] E Berl. (1939) A New Cathodic Process for the Production of H2O2 Trans, Transactions of The Electrochemical Society, 76: 359.
[16] JY Zhang, HC Zhang, MJ Cheng, et al. (2020) Tailoring the Electrochemical Production of H2O2: Strategies for the Rational Design of High-Performance Electrocatalysts, EcoEnergy, 16(15): 1902845.
[17] J Clavilier, D Armand, S Sun, et al. (1986) Electrochemical adsorption behaviour of platinum stepped surfaces in sulphuric acid solutions, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 205(1-2): 2670277.
[18] SY Wang, EB Zhu, Y Huang, et al. (2021) Direct correlation of oxygen adsorption on platinum-electrolyte interfaces with the activity in the oxygen reduction reaction. Science Advances, 7(24): eabb1435.
[19] P Zhang & P Yuan. (2023) Progress of single atom catalysts in electrocatalytic oxygen reduction to H2O2, Chemical Industry Progress, Chemical industry progress, 42(06): 2944-2953
[20] EG Luo, T Tang, Y Wang, et al. (2023) Progress on Tuning the Geometric and Electronic Structure of Precious Metal Catalysts for H2O2 Production via Two-Electron Oxygen Reduction, Applied Chemistry, 40(08): 1063-1076
[21] CH Choi, HC Kwon, S Yook, et al. (2014) H2O2 Synthesis via Enhanced Two-Electron Oxygen Reduction Pathway on Carbon-Coated Pt Surface. The Journal of Physical Chemistry C, 118(51): 30063–30070.
[22] X Zhao, Ha Yang, J Xu, et al. (2021) Bimetallic PdAu Nanoframes for Electrochemical H2O2 Production in Acids, ACS Materials Letter, 3(7): 996-1002.
[23] VF Guilherme, SB Leticia, SFC Eduardo, et al. (2022) Using Palladium and Gold Palladium Nanoparticles Decorated with Molybdenum Oxide for Versatile H2O2 Electroproduction on Graphene Nanoribbons, ACS Applied Materials & Interfaces, 14(5): 6777-6793.
[24] A Yu, GM Ma, LT Zhu, et al. (2022) Electrochemical Reduction of Carbon Dioxide to Carbon Materials for Two-Electron Oxygen Reduction Reaction, Applied Chemistry, 39(04): 657-670.
[25] A Kulkarni, S Siahrostami, A, et al. (2018) Understanding Catalytic Activity Trends in the Oxygen Reduction Reaction, Chemical Reviews, 118(5): 2302-2312.
[26] N Wang, SB Ma, PJ Zuo, et al. (2021) Recent Progress of Electrochemical Production of H2O2 by Two-Electron Oxygen Reduction Reaction, 8(15): 2100076.
[27] JS Lim, JH Kim, J Woo, et al. (2021) Designing highly active nanoporous carbon H2O2 production electrocatalysts through active site identification, Chem, 7(11): 3114-3130.
[28] SC Chen, ZH Chen, S Siahrostami, et al. (2018) Defective Carbon-Based Materials for the Electrochemical Synthesis of H2O2, ACS Sustainable Chemistry & Engineering, 6(1): 311–317.
[29] K Jiang, S Back, AJ Akey, et al. (2019) Highly selective oxygen reduction to H2O2 on transition metal single atom coordination, Nature Communications, 10: 3997.